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I'm new in Painter, so can someone help me where I can find a tut for using the brushes...? I have there is a lot of tools in brush...
When asking questions about Painter, it's very important to be specific, so I'll suggest that you read this tutorial on my Pixelalley site:
How to Ask Corel Painter Questions in Forums Around the Painter Community
Check the rest of my site as there are many tutorials available for individual use by anyone who visits PixelAlley.
Then read Painter's Help Topics, the User Guide in HTML format accessible via the Help menu. You'll find lots of information on using and managing Painter's brushes, using Painter's art materials, and using Painter's other features.
Since you don't say which Painter version you have, I'll suggest another source of tutorials for both Painter IX and Painter X, some of which can be used in earlier versions as well.
The Painter Canvas Newsletter Issues from October 2004 through May 2007
You'll find loads of great tips and tutorials in The Painter Canvas newsletter, in each of the monthly issues.